HandbookChemical Admixture Types

Chemical Admixture Types

IS 9103:1999 / IS 456:2000 Cl. 5.5 · Chemical admixtures — classification, dosage, and performance requirements
Chemical admixtures for concrete classified per IS 9103:1999 (reaffirmed 2018). IS 456 Cl. 5.5 permits admixture use provided they are certified to IS 9103. Dosage is by weight of cementitious material unless stated otherwise. All admixtures must be tested for compatibility with the specific cement and supplementary cementitious materials before site use.
IS 9103
19 items shown
Plasticizers (Type A)
Water-reducing admixtures. Most common type on Indian sites. Based on lignosulphonates or hydroxycarboxylic acids.
TypeIS TypeEffectDosageWater Reduction
Lignosulphonate-basedType AWater reduction while maintaining workability; slight retardation0.2–0.5% by wt of cement5–15%
Hydroxycarboxylic acid-basedType AWater reduction with controlled set retardation0.1–0.3% by wt of cement8–15%
Modified lignosulphonateType AWater reduction with minimal air entrainment0.2–0.5% by wt of cement8–12%
Superplasticizers (Type G/F)
High-range water-reducing admixtures. Essential for M40+ grades and self-compacting concrete (SCC).
TypeIS TypeEffectDosageWater Reduction
Sulphonated Naphthalene Formaldehyde (SNF)Type FHigh water reduction without retardation0.5–2.0% by wt of cement15–25%
Sulphonated Melamine Formaldehyde (SMF)Type FHigh water reduction; very low air entrainment0.5–2.0% by wt of cement15–25%
Polycarboxylate Ether (PCE)Type GVery high water reduction with extended slump retention0.3–1.2% by wt of cement25–40%
Modified PCE (slump-retaining)Type GExtended workability retention for long transit/pumping0.4–1.5% by wt of cement20–35%
Retarders (Type B/D)
Delay initial setting time. Used in hot weather, long-distance RMC, and mass concrete pours.
TypeIS TypeEffectDosageWater Reduction
Sugar-based retarderType BDelays setting by controlled sugar chemistry0.05–0.10% by wt of cementNil
Hydroxycarboxylic acid retarderType BRetardation with mild water reduction0.1–0.4% by wt of cement5–10%
Retarding plasticizerType DCombined water reduction and retardation0.2–0.6% by wt of cement10–15%
Phosphonate-based retarderType BStrong retardation for mass pours and slip-form work0.05–0.15% by wt of cementNil
Accelerators (Type C/E)
Speed up setting and/or early strength gain. Used in cold weather and repair work.
TypeIS TypeEffectDosageWater Reduction
Calcium chlorideType CAccelerates setting and early strength gain significantly1.0–2.0% by wt of cementNil
Calcium nitrite / calcium nitrateType CAccelerates setting; also acts as corrosion inhibitor1.0–3.0% by wt of cementNil
Triethanolamine (TEA)Type CAccelerates early strength; mild effect on setting time0.02–0.05% by wt of cementNil
Calcium formateType EAccelerates hardening with moderate setting acceleration1.0–2.5% by wt of cement5–8%
Sodium thiocyanateType CAccelerates setting in cold weather concreting1.0–3.0% by wt of cementNil
Air-Entraining (Type H)
Introduces microscopic air bubbles (25–250 μm) for freeze-thaw resistance and improved workability.
TypeIS TypeEffectDosageWater Reduction
Vinsol resin-basedType HEntrains 4–7% stable air; improves cohesion and pumpability0.02–0.10% by wt of cementNil (may increase water demand slightly)
Synthetic detergent-basedType HEntrains 3–6% air; improves workability of lean mixes0.01–0.05% by wt of cementNil
Fatty acid salt-based (sodium oleate)Type HEntrains 3–5% air; mild water-repelling effect0.02–0.08% by wt of cementNil
Notes
IS 456 Cl. 5.5.2: Total chloride content in concrete shall not exceed 0.6 kg/m³ for RC and 0.4 kg/m³ for prestressed — effectively bans calcium chloride in reinforced work
Always conduct compatibility test (IS 9103 Annex A) — mix the admixture with the project-specific cement and check setting time, strength, and slump retention before site use
Shelf life of most liquid admixtures is 12 months from date of manufacture; check for sedimentation or colour change before use
Overdose of superplasticizer causes segregation, bleeding, and excessive retardation — never exceed manufacturer's recommended maximum
Overdose of retarder (especially sugar-based) can prevent concrete from setting at all — a 'dead' mix that must be removed and replaced
Admixtures should be added to the mix with the gauging water, not directly on dry cement — direct contact with dry cement causes flash set
In hot weather (>35°C), retarding plasticizer Type D is recommended per IS 7861 Part 1; increase dosage by 25% over normal-weather dosage
Never mix two admixtures in the same container before adding to concrete — always add sequentially via the batching plant dispenser
PCE-based superplasticizers are sensitive to clay content in fine aggregate — wash sand if clay > 3% to avoid dosage escalation
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