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IS 12813 : 1989Method of analysis of hydraulic cement by atomic absorption spectrophotometer

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ASTM C114 · EN 196-2 · JIS R 5202
CurrentSpecializedTesting MethodMaterials Science · Cement, Concrete, Aggregates and RCC
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Link points to Internet Archive / others. Not hosted by InfraLens. Details
OverviewValues5InternationalTablesFAQ4Related

IS 12813:1989 is the Indian Standard (BIS) for method of analysis of hydraulic cement by atomic absorption spectrophotometer. This standard details the procedure for chemical analysis of hydraulic cement using an Atomic Absorption Spectrophotometer (AAS). It serves as a rapid instrumental alternative to the classical wet chemical methods for determining major oxide constituents like SiO2, Al2O3, Fe2O3, CaO, and MgO.

Method of analysis of hydraulic cement by atomic absorption spectrophotometer

Overview

Status
Current
Usage level
Specialized
Domain
Materials Science — Cement, Concrete, Aggregates and RCC
Type
Testing Method
International equivalents
ASTM C114-18 · ASTM International, USAEN 196-2:2013 · CEN (European Committee for Standardization), EuropeJIS R 5202:2018 · JSA (Japanese Standards Association), JapanAS 2350.2-2006 · Standards Australia, Australia
Typically used with
IS 4032IS 269
Also on InfraLens for IS 12813
5Key values4FAQs
Practical Notes
! This standard is now superseded by IS 12813:2018 and should not be used for new testing; the latest version must be consulted.
! Accurate results are highly dependent on the purity of reagents and the precise preparation of standard calibration solutions.
! Complete digestion and dissolution of the cement sample is critical for an accurate analysis; any undissolved residue will lead to under-reporting of constituents.
Frequently referenced clauses
Cl. 4ReagentsCl. 5Preparation of Standard SolutionsCl. 6Preparation of Sample SolutionCl. 7ProcedureCl. 8Calculation
Pulled from IS 12813:1989. Browse the full clause & table index below in Tables & Referenced Sections.
cementhydraulic cementportland cement

International Equivalents

Similar International Standards
ASTM C114-18ASTM International, USA
HighCurrent
Standard Test Methods for Chemical Analysis of Hydraulic Cement
Provides AAS procedures within a broader standard for the chemical analysis of the same cement oxides.
EN 196-2:2013CEN (European Committee for Standardization), Europe
HighCurrent
Methods of testing cement - Part 2: Chemical analysis of cement
Specifies AAS as an alternative method for determining major oxides, with XRF and wet chemistry as reference methods.
JIS R 5202:2018JSA (Japanese Standards Association), Japan
HighCurrent
Methods for chemical analysis of cements
A comprehensive standard for cement chemical analysis that includes AAS as one of the accepted instrumental methods.
AS 2350.2-2006Standards Australia, Australia
MediumCurrent
Methods of testing cement and fly ash - Chemical composition
Covers chemical analysis of cement, referencing AAS, but is broader by including fly ash and other methods like XRF.
Key Differences
≠IS 12813 is a standalone standard dedicated solely to AAS, whereas modern international standards like ASTM C114 and EN 196-2 incorporate AAS as one of several optional methods (alongside XRF, ICP-AES, and reference wet chemistry) within a larger, comprehensive document.
≠In ASTM C114 and EN 196-2, AAS is designated as a 'rapid' or 'alternative' method, with wet chemistry or XRF often serving as the 'referee' method for dispute resolution. IS 12813 (from 1989) presents AAS as a primary instrumental method without this hierarchical distinction.
≠International standards like ASTM C114 offer more varied and robust sample decomposition options, such as lithium metaborate fusion, to ensure complete dissolution of all phases, including silica. IS 12813's primary method is acid digestion, which can be less effective for refractory components.
≠Modern international standards are more performance-based, requiring labs to validate their procedures using Certified Reference Materials (CRMs). IS 12813 is more prescriptive, detailing specific concentrations for standard solutions and calibration curves.
Key Similarities
≈All standards are based on the identical principle of atomic absorption spectrophotometry: measuring light absorption by ground-state atoms in a flame to determine elemental concentration.
≈Both IS 12813 and its international counterparts analyze the same set of major oxides essential for cement characterization: SiO₂, Al₂O₃, Fe₂O₃, CaO, MgO, Na₂O, and K₂O.
≈The use of a hotter nitrous oxide-acetylene flame for refractory elements like Silicon (Si) and Aluminum (Al) and a cooler air-acetylene flame for other elements like Calcium (Ca) and Magnesium (Mg) is a common practice across all standards.
≈All standards mandate the use of a releasing agent, typically a Lanthanum salt solution, to suppress chemical interferences during the analysis of Calcium and Magnesium.
Parameter Comparison
ParameterIS ValueInternationalSource
Flame for Ca, Mg analysisAir-acetyleneAir-acetyleneASTM C114-18
Flame for Si, Al analysisNitrous oxide-acetyleneNitrous oxide-acetyleneASTM C114-18
Interference suppressant for CaO/MgOLanthanum solutionLanthanum or Strontium salt solutionEN 196-2:2013
Primary Sample DecompositionHydrochloric acid (HCl) digestionHCl digestion or Lithium metaborate (LiBO₂) fusionASTM C114-18
Wavelength for Calcium (Ca)422.7 nm422.7 nmASTM C114-18
Wavelength for Silicon (Si)251.6 nm251.6 nmASTM C114-18
Wavelength for Magnesium (Mg)285.2 nm285.2 nmEN 196-2:2013
⚠ Verify details from original standards before use

Key Values5

Quick Reference Values
Wavelength for Silicon (Si) determination251.6 nm
Wavelength for Aluminum (Al) determination309.3 nm
Wavelength for Iron (Fe) determination248.3 nm
Wavelength for Calcium (Ca) determination422.7 nm
Wavelength for Magnesium (Mg) determination285.2 nm
Key Formulas
Percentage of oxide = (C × V × D) / (W × 10) — General formula for calculating percentage of oxide from concentration

Tables & Referenced Sections

Key Tables
No tables data
Key Clauses
Clause 4 - Reagents
Clause 5 - Preparation of Standard Solutions
Clause 6 - Preparation of Sample Solution
Clause 7 - Procedure
Clause 8 - Calculation

Related Resources on InfraLens

Cross-Referenced Codes
IS 4032:1985Methods of Chemical Analysis of Hydraulic Cem...
→
IS 269:2015Ordinary Portland Cement - Specification
→

Frequently Asked Questions4

What is the principle of this test method?+
The method is based on measuring the absorption of radiation by ground-state atoms in a flame, where the amount of absorption is proportional to the concentration of the element in the sample.
Is this a destructive test?+
Yes, a sample of cement is dissolved in acids for the analysis and cannot be recovered.
Which oxides can be determined using this standard?+
The standard covers the determination of silicon dioxide (SiO2), aluminium oxide (Al2O3), ferric oxide (Fe2O3), calcium oxide (CaO), and magnesium oxide (MgO).
Is this standard still valid?+
No, IS 12813:1989 has been superseded by the 2018 revision, IS 12813:2018.

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